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Silicone vs EPDM

Jehbco manufactures products from 100% silicone.  Often, there are a range of materials to choose from for your application – is Jehbco’s silicone the right one? In this article, we’ll explore the differences between silicone and one of its competitors – EPDM.  Silicone and EPDM are both common materials for o-rings, gaskets, seals, hoses and membranes.  The two materials have many similar properties.  Which one is right for your application?  Let’s take a closer look at the differences between the two.

Silicone and EPDM both exhibit good chemical resistance, excellent weathering resistance and good temperature resistance.  However, their properties are not the same, and, depending on the conditions of the application, one will be a better choice than the other.  The table below summarises some of the key differences between the two materials.

 

EPDM Silicone
-50 °C to 150 °C -50 °C to 230 °C
Great compression set Excellent compression set
Excellent weather resistance Excellent weather resistance
Approx. tensile strength 14 MPa Approx. tensile strength 5 MPa
Good abrasion resistance Poor abrasion resistance
Not compatible with: oils, greases, hydrocarbon fuels, aromatic hydrocarbons, concentrated acids, halogenated solvents. Not compatible with: hydrocarbon fuels, alkalis and acids, steam over 121 °C, trichloroethylene, aromatic hydrocarbons.
Compatible with: hot and cold water, alkalis, dilute acids, steam, ketones, fireproof hydraulic fluids. Compatible with: oils, brake fluids, hot and cold water, salt water, high molecular weight chlorinated hydrocarbons, fire resistant hydraulic fluid, ozone.

 

Both materials are able to operate over a wide range of materials.  EPDM and silicone both maintain flexibility down to approximately -50 °C, making both materials a good choice for low temperature applications.  However, silicone can withstand temperatures almost 100 °C higher than EPDM – up to 230 °C.  For high temperature applications, silicone is the best choice.

EPDM has high tensile strength and good abrasion resistance.  While silicone has good tensile strength, its abrasion resistance is not high, and for applications involving movement and friction, EPDM may be a better choice.  Silicone can be formulated to have improved tear strength, making it an ideal choice for applications such as vacuum sheeting.

Both EPDM and silicone have excellent resistance to ozone and UV.  EPDM is not recommended for use with oils and greases. While silicone does exhibit some swelling when exposed to oils, it is rated as compatible with oils and greases and is a better choice for applications involving these chemicals.  EPDM is compatible with alkalis and dilute acids, but is not resistant to concentrated acids.  Silicone has poor resistance to alkalis and acids, making EPDM the better choice for acid and alkali applications.  Neither material is compatible with hydrocarbon fuel, but silicone is resistant to automotive brake fluids.

While both materials exhibit good compression set, silicone has less compression set than EPDM.  This makes silicone a better choice for applications requiring a long lasting, reusable seal.

While silicone outperforms EPDM in some areas, both materials exhibit good properties and the right choice will depend on your individual application.  For help selecting a material for your application, consult our website www.Jehbco.com.au and contact us with any questions.

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How Coefficient of Friction Changes

Jehbco manufactures custom engineered silicone extrusions to suit your application’s requirements.  Our engineers take every effort to ensure that our silicone’s properties match your application perfectly.

An important property of silicone is the coefficient of friction (CoF), which describes how hard it is to slide the silicone along a surface.  The CoF affects many areas: examples include the forces in moving seal systems (for example, o-ring seals on pistons); the ability of a seal to remain in place without adhesive; and the compression of a gasket between two hard surfaces.

In a previous article, we discussed how the coefficient of friction is measured.  In this article, we’ll look at what factors influence the CoF and how it can be tailored to your application.

The coefficient of friction is a property of the entire system, not only the silicone.  In general, the coefficient of friction will be higher (that is, sliding will be more difficult) when silicone is in contact with a rough surface than when silicone is in contact with a smooth surface.  The material itself will also affect the coefficient of friction – silicone will slide less against a smooth piece of aluminium than against a smooth piece of Teflon.

 

Figure 1: Measuring coefficient of friction.

Figure 1: Measuring coefficient of friction.

 

One important system property that can affect the coefficient of friction is temperature.  As the temperature decreases, the silicone becomes slightly less soft.  This causes the coefficient of friction to decrease very slightly.  In addition, lower temperatures may produce condensation.  A thin film of water on the surface of the silicone will act as a lubricant and further lower the coefficient of friction, causing the silicone to slide more easily.

Silicone is naturally quite tacky, with a coefficient of friction of approximately 1.0 in many cases.  On many of our products, processes are applied to reduce the coefficient of friction.  These processes include applying a small amount of talc to the silicone surface and post curing the silicone in an oven for several hours.  In general, harder silicones with a higher durometer have a lower coefficient of friction, and our platinum silicone material has a lower coefficient of friction.

Jehbco’s engineers are able to tailor the properties of our silicone to produce a coefficient of friction that meets your requirements, and we have in-house testing capabilities that allow us to measure the coefficient of friction.  For any help with your application please review the Jehbco website www.Jehbco.com.au, and contact us with any questions.

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Silicone as a Sealing Material

Wherever liquids and gasses are encountered in machinery and construction, mechanical seals are required.  Jehbco produces custom silicone mechanical seals for a variety of applications. Mechanical seals prevent fluids (liquids and gasses) entering between two parts, and they are essential for many man-made things: fuel systems in cars, roofing on houses, taps, fridge door seals – the list goes on!

Silicone as a Sealing Material

Silicone as a Sealing Material

Many sealing systems incorporate a soft, flexible part that, when placed under load, deforms slightly to fill the gaps and irregularities between two hard parts.  These parts generally fall in two categories:

Gaskets: a general term used for a part that is pressed between two harder parts.  The part may have any shape, although flat gaskets are common.  An everyday example is the door seal in a fridge.

O-rings: these are a special type of gasket that are circular and have a round profile (like a doughnut).   O-rings are designed to fit into a groove in one of the parts and are very common in machinery.

Gasket materials must withstand the environment they are to be used in, the fluids they are to seal and the mechanical wear and tear of the application.

Silicone has a range of properties that makes it ideal for many sealing applications:

Temperature range: silicone is able to operate over a very wide range of temperatures, from -50°C to 230°C.

Chemical resistance: silicone is resistant to a wide range of chemicals: engine oil, animal and vegetable oils, brake fluid, fresh and salt water, flame resistant insulators and ozone.  Silicone is not compatible with hydrocarbon fuels, acids or alkalis.

Durability: silicone is UV resistant and exhibits extremely good weathering characteristics.

Low swelling: silicone exhibits a low level of swelling – when exposed to a variety of chemicals, the increase in volume of the silicone seal is low.

The one downside of silicone is its relatively poor resistance to abrasion and tearing.  However, silicone makes an excellent choice for seals in static applications, where the seal will not be continually rubbed or abraded.

Jehbco has produced silicone gaskets for a range of static sealing applications, including light aircraft door seals, where a large temperature range is required; marine door and window seals, where excellent weathering resistance is required; drinking water, food and medical gaskets, requiring excellent chemical resistance; gaskets for electrical enclosures; and o-rings for salt water piping, to name only a few of our applications! For any help with your application please review the Jehbco website www.Jehbco.com.au, and contact us with any questions.

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The Stress / Strain Curve

Jehbco’s pure silicone extrusions are used in a wide range of applications, from aircraft seals to sea water piping gaskets.  These applications present a wide range of operating conditions that our silicone must work under, and Jehbco works with our customers to ensure the best silicone product is chosen for your application.

In order to determine the best silicone for your application, we must be able to measure the performance of our silicone.  A range of material properties are tested to describe how our silicone will perform under different conditions.  Several of these properties are measured using a stress/strain curve.

The stress/strain curve

The stress/strain curve

The stress/strain curve is created by stretching a piece of silicone and measuring both the force required to stretch the silicone (tensile force) and how much it stretches (elongation).  The silicone is stretched until it breaks.  Since the silicone samples being stretched can be different sizes, the tensile force and elongation measurements are corrected.  Tensile force is divided by the cross sectional area of the silicone to get stress and elongation is divided by the original length of the silicone to get strain.  Stress is plotted on the y-axis and strain is plotted on the x-axis to get a stress/strain curve.   An example stress/strain curve is shown  below.

From the stress/strain curve, we can determine several important mechanical properties that tell us how the silicone behaves.  The modulus of the silicone tells us how stiff the silicone is, or how hard it is to stretch.  This is measured by calculating the slope of the first part of the stress/strain curve.  Stiff silicones will have a very steep curve, while softer silicones will have a shallower curve.

The tensile strength of the silicone is the amount of stress, or normalised force, needed to break the silicone.  This is easily read off the stress/strain curve – it is the stress at the very end of the curve, where the silicone breaks.

To ensure our product works as required, it is important that properties such as modulus and tensile strength are right for the application.  Jehbco has in-house facilities for generating stress/strain curves, to help us tailor the right product for your application.

 

For any help with your application please review the Jehbco website www.Jehbco.com.au, and contact us with any questions.

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Measuring Sealing Force

Measuring Sealing Force

Seals are used to prevent the ingress of fluid or particles in a wide range of mechanical applications.  Applications vary from traffic light enclosures to hydraulic mining equipment, fluids range from seawater to DOT brake fluid and pressures range from a couple of kilopascals to hundreds of megapascals. While some applications have been standardised, many seals require individual design.  Jehbco manufactures custom silicone extrusions for a range of non-standard sealing applications.

Seal performance is influenced by a number of factors.  These include:

  • The nature of the fluid being sealed, whether it be liquid or gas;
  • The condition of the sealing surfaces and presence of any grooves or roughness;
  • Materials;
  • Geometry;
  • Force exerted on the sealing surfaces.

This last factor, sealing force, is useful not only in estimating performance, but is essential for proper design of the sealing system.  For example, in a gasket system (Figure 1), sealing force is exerted on the gasket by a series of bolts.  To design the bolting system, the designer must know the force required to compress the gasket and form a seal.

 

Figure 1: A gasketted flanged pipe joint.

Figure 1: A gasketted flanged pipe joint.

 

Sealing force is often determined through guesswork and expensive in-field testing.  Jehbco are breaking this mould by developing custom tooling to measure force on our sealing products.  With these tools, Jehbco will be able to provide our customers with accurate estimates of sealing force required under specific conditions – for example, the force required to compress an o-ring by 20%, or the force exerted by a seal on an expansion joint when the joint is 10 mm wide.  Jehbco aims to use these tools to enhance your design processes so we can more quickly produce a silicone extrusion that meets your sealing requirements.

For more information on silicone seals and assistance, please contact us at Jehbco.

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Exploring Silicone Rubber “Blooming”

Providing a unique balance of the chemical and mechanical properties required by many of today’s more demanding industrial requirements; Silicone Rubber continues to excel in many applications from architecture to healthcare.

“Blooming” refers to the milky discoloration or white powder caused by the migration of compounds to the surface of the rubber. The presence of by-products or excess compounds can cause blooming, affecting both the functionality and aesthetics of the silicone rubber. Depending on the application, utmost purity and cleanliness of materials are essential, i.e. healthcare applications, or material aesthetics become a major material selection driving force, i.e. architecture design applications.

Exploring Silicone Rubber “Blooming”

Exploring Silicone Rubber “Blooming”

Most silicone rubber, among other silicone products, are derived from the same chemical starting material and are later differentiated. Depending on the application, tailored silicone rubber properties can be achieved through various mechanisms, such as the addition of fillers, functional fluids, and curing agents.

Curing; an essential process as to convert silicone rubber to solid from its highly-adhesive gel or liquid uncured state, is normally achieved in a catalyst-driven two-stage process; at the point of manufacture into the desired shape, and further in a prolonged post-cure process.

The choice of the catalyst system, either addition or peroxide, significantly affects the production of by-products. Addition curing system, i.e. platinum-based catalyst, the curing occurs with no byproducts, while peroxide-based curing system leaves behind byproducts, which can be an issue in food and medical applications. Both the solubility of any added fillers or agents, along with the presence of byproducts developed during curing, influence what is known as ‘Blooming’. Generally, each curing method has its own advantages and disadvantages, and based on the required end-product material properties, an optimised design selection is selected.

Accordingly, it is essential to select a reputable silicone manufacturer known for their high grades of raw materials and silicone expertise (we meet these requirements at Jehbco). By tailoring the process design per application, silicone can meet and exceed blooming and other requirements.

Overall, blooming can be influenced by the presence of added-materials to the silicone for enhanced properties and/or processability, along with the byproducts developed during the curing process.

For any help with your application, please review the Jehbco website www.jehbco.com.au, and contact us with any questions

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Fire resistance, thermal degradation and heat stabilisers – what do all of these mean?

Silicone rubber has an outstanding reputation for being a reliable, durable construction material with a higher melting point and ignition point than other common polymers such as PP and PVC. These properties make silicone an excellent choice of material for use in high temperature applications. A handful of silicone manufacturers, including here at Jehbco, can enhance the high temperature performance of silicone rubber by including fire resistant additives or heat stabilisers in the silicone manufacturing process. But how do these additives affect the final silicone product, and in which applications should they be used?

When silicone rubber is exposed to high temperature environments for extended periods, as expected in automotive, refrigeration and certain electrical applications, they will lose their elasticity and flexibility, becoming brittle before ultimately tearing. In industry, this is measured by the high temperature exposure time required for the rubber to lose one half of its standard elongation at room temperature. Typically, general silicone rubber can be used indefinitely at temperatures below 150oC, for 1000 hours at temperatures around 200oC and for short periods of time at 350oC and above before breaking. Traditional heat stabilisers such as cerium oxide or titanium dioxide inhibit silicone oxidation, which slows the degradation process by over 100 orders of magnitude. This helps preserve the elasticity and elongation and increase the lifetime of the silicone product.

 

Fire resistance, thermal degradation and heat stabilisers

Fire resistance, thermal degradation and heat stabilisers

 

When exposure to fire or temperatures around silicone’s autoignition point (>450oC) becomes a possibility, then the products’ resistance to thermal degradation and fire resistance need to be considered.  Resistance to thermal degradation refers to the initial ignition point of the material and describes how the rubber will behave when exposed to radiated heat. This is best pictured by thinking of a piece of silicone in a room with a very high temperature. The ability of silicone to withstand igniting at this elevated temperature is its resistance to thermal degradation, and can be quantified under standards such as the AS 1530.3 and EN 45545 standards. These standards measure the temperature and time taken to ignite, the smoke released from the material, time taken to extinguish and amount of heat released during combustion. Which of these measurements is most relevant will vary depending on application. Flame or fire resistance typically refers to the behavior of silicone when directly exposed to a flame. This is frequently standardised using the UL 94 test which measures how long the sample will take to ignite, and how long it takes to extinguished after being immersed in a hot flame. Additives can be used to influence the way silicone combusts in extreme temperatures or in contact with flame, including a variety metal hydroxides which release water vapour upon combustion to cool the subsequent flame, and other additives being developed and tested at Jehbco.

With all this in mind, deciding which blend of additives to use for any application can be difficult. Jehbco offers a unique range of fire additives and expertise in manufacturing fire resistant silicones that are can be custom engineered to suit most specific applications. Many of Jehbco’s existing products are already certified under various international fire safety standards to ensure peace of mind.  For more information about heat stabilisers and fire additives, please visit our website and contact us with any questions.

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Silicone Hardness and Shore Durometer

Jehbco’s silicone extrusions are used in a wide range of applications, from aircraft seals to medical grade tubing.  To make sure you have the right silicone for your application, the application requirements have to be closely matched to the silicone properties.  There are many material properties that may affect our silicone’s performance in your application.  One of the most important properties is hardness or “durometer”.

The hardness of a material refers to how easily the material resists deformation under compression.  Put more simply, if something is pressed against the surface of a material, hardness tells us how easily the material is deformed or marked.   Depending on the material, there are several standard tests that can be used to determine hardness.  Metals are often tested using the Vickers or Rockwell procedures – these press a small tool into the surface of the metal under a standard load and measure the size of the resulting mark.

For elastomers such as silicone, hardness is measured using the Shore Durometer test.  This test measures the depth that a small cone can be pressed into the surface of the silicone.  The depth that the cone sinks into the silicone is converted to a value on the Shore Durometer scale.  The cone sinks deeper into soft silicones and these have a low value on the scale.  If the silicone is hard, the cone doesn’t sink very far and the value on the Shore scale is high.

 

Silicone hardness and the Durometer Scale with Jehbco Silicones

Silicone hardness and the Durometer Scale with Jehbco Silicones

 

There are several variations of the Shore Durometer test for different types of elastomers.  The most common are Shore Durometer A for soft elastomers and Shore Durometer D for hard elastomers.  Each test gives a hardness value from 0 to 100.  The Shore A test is generally used to measure the hardness of Jehbco silicones – most of our silicones fall between 25 and 80 Duro Shore A.  Jehbco has equipment to test Shore hardness to the ASTM D2240 standard.

To get an idea of what the different hardness scales mean, 25 Duro silicone can be easily compressed with your fingers – think of the rubber that rubber bands are made of.  80 Duro silicone is much harder to compress, more like the rubber in a shoe sole.

To ensure that the silicone you choose for your application performs as required, it must have the right durometer.  For applications such as vacuum sheeting, a low durometer might be just right, while gaskets may require a medium to high durometer.  Jehbco can tailor a silicone material to the durometer required for your application.

For any further questions about how durometer will affect your application please contact our sales team.

 

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Silicone Tear Strength

Silicone Tear Strength

Jehbco’s extruded silicone products are used in a multitude of application areas, and we have a range of silicone grades to suit every application.

When selecting a silicone grade for your application, it is essential to determine the tear strength required.  Tear strength measures a material’s ability to resist failure by tearing.  For polymers such as silicone, this is determined by measuring the speed of growth of existing cracks when the material is placed under tension.  This is measured in Newtons of tensile force per millimetre of product thickness.  Tear strength not only measures how easily a material will fail by tearing when placed under load, but provides an indication of the abrasion and wear resistance of the material.

If the tear strength is lower than required, silicone can suffer from wear and form cracks and tears.  Applications such as piping in the food and beverage industries, gaskets, seals and vacuum blankets require silicone free from wear and cracks.  In the best case, cracks and tears will reduce the product longevity.  In the worst case, these cracks and tears can cause product failure, leakage and damage to other parts of the system.

 

Figure 1: Jehbco high tear silicone sheeting for vacuum blankets.

Figure 1: Jehbco high tear silicone sheeting for vacuum blankets.

 

By selecting a silicone with sufficient tear strength, the danger of product failure can be avoided.  A good first step in determining the tear strength required for your application is to look at similar applications and the tear strength of the materials used, measured in N/mm.  Jehbco produce a range of silicones with different tear strengths to suit many applications.

Tear strength is an important material property and Jehbco can tailor a silicone product to the tear strength requirements of your application.  For any help with your application please review the Jehbco website www.Jehbco.com.au, and contact us with any questions.

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Coefficient of Friction of Silicone Extrusions

Friction is the force opposing movement when two materials make contact.  Knowledge of friction is essential for many of our customers’ applications:

  • it determines forces in moving systems such as O’Rings seals,
  • it describes the ability of a seal to remain in place without adhesive
  • it affects the compression of a gasket when pressed between two metal surfaces.
Figure 1: Friction force on a block

Figure 1: Friction force on a block

Figure illustrates the frictional force on a block resting on an incline.  Gravity pushes the block down the incline, and friction opposes this force.  Friction is a phenomenon that is still not understood completely, and frictional force cannot be calculated using any theoretical equation – it must be measured directly for the system of interest.  A surprising and useful empirical result is that frictional force depends only on the force pushing materials together and not on their area of contact.  This is because friction is due to atomic contact between surfaces. The area of atomic contact is very small and depends above all upon the force between surfaces, not their areas.

The coefficient of friction is the ratio of friction force to normal force.  Most material combinations show two types of friction – a strong frictional force when the materials are not sliding (static friction), and a weaker force when they are sliding (kinetic friction).  Different methods are used to measure each type of friction.

To measure the static coefficient of friction, the two materials can be tilted (as in Figure 1) until one of the materials begins to slide.  The static coefficient of friction is the tangent of the angle of tilt when the materials start sliding.

Measuring the kinetic coefficient of friction is more involved, and requires careful measurement of the force required to keep two materials sliding at a constant speed.  Many test rigs have been designed for this.  The most important factor is that the test conditions match application conditions as closely as possible to ensure results are relevant to the application.

Jehbco have developed in-house testing procedures and facilities to measure the coefficient of friction in customer applications.  If friction is important in your application, we can tailor a test to your application conditions and give detailed information on the performance of our products.

For any help with your application please review the Jehbco website www.Jehbco.com.au, and contact us with any questions.

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