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Silicone Extrusions in the Rail Industry

Silicone is a versatile material with excellent properties.  As such, silicone is a valuable material in many industries, and Jehbco manufactures silicone extrusions for a range of applications.  One key application area is rail transport.

Trains are complicated pieces of machinery which are required to run frequently and reliably for many years of service.  There are many parts of a train requiring an elastomer material and often these parts are subject to severe operating conditions.  For example, door seals see repeated deformation and are exposed to the weather, while seals in engine compartments are subject to high temperatures and exposed to oil.  For many of these parts, silicone is a natural choice.

Rail applications are safety critical, and all materials used in trains must conform to strict standards on fire safety.  Historically, toxic smoke in train crashes has led to increased fatalities, and modern trains are constructed from materials that do not produce toxic smoke, so as to avoid this hazard.  Jehbco’s silicone extrusions are able to meet national and international standards on flame resistance and smoke toxicity.  This is a key reason for our silicone’s widespread use in train construction.

 

 

Silicone exhibits a range of other desirable properties.  Silicone is flexible, strong, and extremely durable, being resistant to UV and ozone.  This range of properties makes Jehbco’s silicone extrusions ideal for a number of internal and external applications, including door seals, window seals, HVAC gaskets and sealing of electronic enclosures.

Silicone is an elastomer, or flexible rubber.  This means silicone is able to dampen vibrations and sound.  Silicone sheeting is used in train walls and ceilings as sound insulation, and in other areas to dampen vibrations and increase passenger comfort.

Jehbco’s silicone can operate over an extremely large range of temperatures (from -50 °C to 230 °C), allowing it to be used for sealing applications near engines and other hot mechanical components.  Silicone is unaffected by water, brake fluids and oils, making it a good choice for many applications requiring flexible tubing.

The properties of Jehbco’s silicone make it an ideal choice for many train parts.  But is the shape and size of our product right for the application?  Jehbco is able to custom engineer a silicone extrusion to any shape and size, and we work with our customers to design the perfect fitting part for any application.

For more details on Jehbco’s silicone extrusions and their applications, consult our website www.Jehbco.com.au and contact us with any questions.

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Silicone vs Nitrile

When designing your next product, there are a myriad of elastomer materials to choose from.  Jehbco manufactures all our products from 100% silicone.  Is silicone the right elastomer for your application?  In this article, we’ll explore the differences between silicone and a common competitor – nitrile – and clarify which material is the best choice for your design.

Acrylonitrile-butadiene, commonly known as nitrile or NBR, has excellent chemical resistance, similar to silicone.  However, the two materials differ in many of other properties.  The table below summarises some of their key differences.

 

NBR Silicone
-57 °C to 121 °C -50 °C to 230 °C
Great compression set Excellent compression set
Poor weather resistance Excellent weather resistance
Approx. tensile strength 15 MPa Approx. tensile strength 5 MPa
Good abrasion resistance Poor abrasion resistance
Not compatible with: ozone, ketones, esters, aldehydes, chlorinated hydrocarbons, brake fluid, concentrated acids. Some formulations are not food grade. Not compatible with: hydrocarbon fuels, alkalis and acids, steam over 121 °C, trichloroethylene, aromatic hydrocarbons.
Compatible with: hot and cold water, petroleum-based oils and fuels, silicone greases, hydraulic fluids, alcohols, weak acids and alkalis. Compatible with: ozone, oils, brake fluids, hot and cold water, salt water, high molecular weight chlorinated hydrocarbons, fire resistant hydraulic fluid.

 

Both silicone and nitrile exhibit excellent resistance to cold temperatures, remaining flexible down to -50 °C, with special formulations of nitrile remaining flexible to -57 °C (at the expense of other physical properties such as wear resistance). Nitrile can operate to 100 °C, or 121 °C with reduced longevity.  Silicone can operate at much higher temperatures, up to 230 °C.  This makes silicone the best choice for high temperature applications.

Both materials are resistant to a range of chemicals.  Nitrile has excellent resistance to hydrocarbon fuels and oils, making it ideal for automotive fuel applications.  Formulations of nitrile containing phthalate plasticizers cannot be used with food or children’s toys.  Silicone, on the other hand, is food grade and is often used in food and water processing equipment.  For any application, it is important to check that the elastomer is resistant to the chemicals it will come into contact with.

Nitrile has high tensile strength and excellent wear and abrasion resistance.  By contrast, silicone has poor abrasion resistance, and for dynamic applications where elastomers must have good wear characteristics, nitrile is a better choice.

Nitrile exhibits poor resistance to weathering, UV and ozone, making it unsuitable for outdoor applications.  Silicone has excellent weathering characteristics and is highly resistant to both ozone and UV.  For outdoor applications, silicone is a clear winner.

While both materials exhibit good compression set, silicone generally undergoes less compression set than nitrile. This makes silicone a better choice in sealing applications where a long-lasting, reusable seal is required.

For help selecting a material for your application, please contact us with any questions.

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Peroxide Curing in Silicone Manufacturing

An important part of the silicone manufacturing process is the kind of catalyst used to create the product. During production, a catalyst is added to make the silicone cure, which hardens and sets the final product. Typically, a peroxide catalyst is the cheapest and most common catalyst used to manufacture silicone gaskets, o-rings, strips and cords in the construction sector. The kind of catalyst used can have a significant impact on the product’s appearance, physical behaviour and chemical properties. Thus, it is important to understand how different catalysts can affect the properties of peroxide cured silicone. At Jehbco, we work with our clients to ensure that the ideal catalyst is used to deliver the best silicone product for your application.

 

Silicone Chemistry with Jehbco Silicones

Silicone Chemistry with Jehbco Silicones

 

By definition, a catalyst is a substance that facilitates a forward chemical reaction without being depleted as the reaction takes place. The first step in a peroxide cure is the spontaneous formation of peroxide radicals. These peroxide radicals then break double bonds in the silicone chain structure. The site where the double bond is broken is free to form a single bond with various chemical groups on another silicone chain through a variety of reaction pathways. The bonds that stretch between silicone chains forms a cross-link. This cross-linking between silicone chains is what causes an increase in toughness in the curing process.

 

Reaction Chain with Jehbco Silicones

Reaction Chain with Jehbco Silicones

 

Above: An example reaction to illustrate the formation of a cross-link between two separate silicone chains. The peroxide catalyst allows the double bond to be broken.

A side effect of peroxide curing is a phenomenon known as ‘blooming’. This occurs when the left-over catalyst migrates to the surface of the silicone, forming a powdery white substance or ‘bloom’. This bloom primarily consists of volatile organic acids. Due to this phenomenon, peroxide cured catalysts undergo a post-curing process where they are heated in a controlled and ventilated environment at 200OC for 4 hours. This process removes all of the catalyst and other extractables from the silicone, leaving behind a pure silicone rubber product. However, peroxide cured catalyst unsuitable for food grade applications, as any minuscule amount of extractables left in the silicone is undesirable due to contamination concerns.

The addition of around 1-1.5% w/w of peroxide catalyst to a silicone mixture is enough to facilitate cross-linking. The small amount of catalyst required, as well as the lower cost of peroxide catalyst, is what makes it useful and effective for silicone manufacturing. Peroxide cured silicones are typically more rigid than platinum cured silicones, making them an ideal material for construction or transportation applications. Peroxide cured silicones are often more opaque and sometimes darker than platinum cured silicone.

Ultimately, cross-linked, peroxide cured silicone is a strong, versatile material that is used to manufacture a variety of products. Deciding whether or not peroxide cured silicone is best for your application can depend on a number of factors, but it is most important to think about the cost of the product, product appearance and whether or not food grade silicone is required. At Jehbco we offer both peroxide and platinum cured silicones for an extensive range of applications and industries.

For further information or advice about which silicone rubber best suits your application, please review the Jehbco website www.jehbco.com.au, and contact us with any questions.

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Talc and Silicone Extrusions

Jehbco manufactures custom silicone extrusions in our Sydney-based factory, carrying out all steps in-house, from product design and development to die cutting, material preparation and manufacture.  This gives us fine grained control over the properties and quality of the final product, allowing us to tailor each product to the requirements of our varied customer base.

Jehbco’s manufacture of silicone extrusions is a process with several steps.  The raw silicone material is first mixed and then fed to an extruder.  The extrusion that comes from the extruder is passed through several stages of heating and then boxed or coiled.  Finally, extrusions are placed in an oven for several hours to post-cure.  The post-cure process reduces the stickiness of silicone, as well as removing volatiles and improving other properties.

In its raw form, silicone is quite sticky.  While some applications require a high degree of stick and friction, such as gaskets which must be retained in joints without additional adhesive, many applications require lower friction than silicone naturally has.  For example, o-rings must slide easily against machine parts and some seals must slide easily into a joint.

A problem with silicone’s natural stickiness is the tendency of some silicones to self-adhere when coiled.   The coils of silicone extrusion may stick to each other, which can lead to tearing of thin sections during uncoiling.   As extrusions are coiled prior to post-curing, the post-curing process does not solve the issue of self-adherence.

To reduce the stickiness of our extrusions, both for low friction applications and to eliminate the risk of self-adherence, we use a talcing process.  After curing and before coiling, a thin layer of talc is applied to the surface of the extrusion.  This layer of talc acts as a lubricant and prevents the extrusions from self-adhering when coiled.  The talc does not react with the silicone and has no effect on the material properties of the extrusion; it only serves to reduce surface friction.

While the talcing process has previously been done by hand, Jehbco are currently implementing an automated talc application process.  This will allow quicker application of a more even and consistent layer of talc on our extrusions.

 

Figure 1: An extrusion passing through Jehbco’s new talc applicator

 

On the other side of the coin, some applications require higher friction than our standard extrusions can offer.  Not a problem! Jehbco can increase the coefficient of friction of our silicone in a number of ways: specifying softer (lower durometer) silicone, different grades of silicone and removing the post-cure process.

Jehbco makes every effort to ensure our product fits your application, from profile design to material properties.

For help matching our products with your application, please review our website www.Jehbco.com.au and contact us with any questions.

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Silicone vs EPDM

Jehbco manufactures products from 100% silicone.  Often, there are a range of materials to choose from for your application – is Jehbco’s silicone the right one? In this article, we’ll explore the differences between silicone and one of its competitors – EPDM.  Silicone and EPDM are both common materials for o-rings, gaskets, seals, hoses and membranes.  The two materials have many similar properties.  Which one is right for your application?  Let’s take a closer look at the differences between the two.

Silicone and EPDM both exhibit good chemical resistance, excellent weathering resistance and good temperature resistance.  However, their properties are not the same, and, depending on the conditions of the application, one will be a better choice than the other.  The table below summarises some of the key differences between the two materials.

 

EPDM Silicone
-50 °C to 150 °C -50 °C to 230 °C
Great compression set Excellent compression set
Excellent weather resistance Excellent weather resistance
Approx. tensile strength 14 MPa Approx. tensile strength 5 MPa
Good abrasion resistance Poor abrasion resistance
Not compatible with: oils, greases, hydrocarbon fuels, aromatic hydrocarbons, concentrated acids, halogenated solvents. Not compatible with: hydrocarbon fuels, alkalis and acids, steam over 121 °C, trichloroethylene, aromatic hydrocarbons.
Compatible with: hot and cold water, alkalis, dilute acids, steam, ketones, fireproof hydraulic fluids. Compatible with: oils, brake fluids, hot and cold water, salt water, high molecular weight chlorinated hydrocarbons, fire resistant hydraulic fluid, ozone.

 

Both materials are able to operate over a wide range of materials.  EPDM and silicone both maintain flexibility down to approximately -50 °C, making both materials a good choice for low temperature applications.  However, silicone can withstand temperatures almost 100 °C higher than EPDM – up to 230 °C.  For high temperature applications, silicone is the best choice.

EPDM has high tensile strength and good abrasion resistance.  While silicone has good tensile strength, its abrasion resistance is not high, and for applications involving movement and friction, EPDM may be a better choice.  Silicone can be formulated to have improved tear strength, making it an ideal choice for applications such as vacuum sheeting.

Both EPDM and silicone have excellent resistance to ozone and UV.  EPDM is not recommended for use with oils and greases. While silicone does exhibit some swelling when exposed to oils, it is rated as compatible with oils and greases and is a better choice for applications involving these chemicals.  EPDM is compatible with alkalis and dilute acids, but is not resistant to concentrated acids.  Silicone has poor resistance to alkalis and acids, making EPDM the better choice for acid and alkali applications.  Neither material is compatible with hydrocarbon fuel, but silicone is resistant to automotive brake fluids.

While both materials exhibit good compression set, silicone has less compression set than EPDM.  This makes silicone a better choice for applications requiring a long lasting, reusable seal.

While silicone outperforms EPDM in some areas, both materials exhibit good properties and the right choice will depend on your individual application.  For help selecting a material for your application, consult our website www.Jehbco.com.au and contact us with any questions.

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How Coefficient of Friction Changes

Jehbco manufactures custom engineered silicone extrusions to suit your application’s requirements.  Our engineers take every effort to ensure that our silicone’s properties match your application perfectly.

An important property of silicone is the coefficient of friction (CoF), which describes how hard it is to slide the silicone along a surface.  The CoF affects many areas: examples include the forces in moving seal systems (for example, o-ring seals on pistons); the ability of a seal to remain in place without adhesive; and the compression of a gasket between two hard surfaces.

In a previous article, we discussed how the coefficient of friction is measured.  In this article, we’ll look at what factors influence the CoF and how it can be tailored to your application.

The coefficient of friction is a property of the entire system, not only the silicone.  In general, the coefficient of friction will be higher (that is, sliding will be more difficult) when silicone is in contact with a rough surface than when silicone is in contact with a smooth surface.  The material itself will also affect the coefficient of friction – silicone will slide less against a smooth piece of aluminium than against a smooth piece of Teflon.

 

Figure 1: Measuring coefficient of friction.

Figure 1: Measuring coefficient of friction.

 

One important system property that can affect the coefficient of friction is temperature.  As the temperature decreases, the silicone becomes slightly less soft.  This causes the coefficient of friction to decrease very slightly.  In addition, lower temperatures may produce condensation.  A thin film of water on the surface of the silicone will act as a lubricant and further lower the coefficient of friction, causing the silicone to slide more easily.

Silicone is naturally quite tacky, with a coefficient of friction of approximately 1.0 in many cases.  On many of our products, processes are applied to reduce the coefficient of friction.  These processes include applying a small amount of talc to the silicone surface and post curing the silicone in an oven for several hours.  In general, harder silicones with a higher durometer have a lower coefficient of friction, and our platinum silicone material has a lower coefficient of friction.

Jehbco’s engineers are able to tailor the properties of our silicone to produce a coefficient of friction that meets your requirements, and we have in-house testing capabilities that allow us to measure the coefficient of friction.  For any help with your application please review the Jehbco website www.Jehbco.com.au, and contact us with any questions.

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Silicone as a Sealing Material

Wherever liquids and gasses are encountered in machinery and construction, mechanical seals are required.  Jehbco produces custom silicone mechanical seals for a variety of applications. Mechanical seals prevent fluids (liquids and gasses) entering between two parts, and they are essential for many man-made things: fuel systems in cars, roofing on houses, taps, fridge door seals – the list goes on!

Silicone as a Sealing Material

Silicone as a Sealing Material

Many sealing systems incorporate a soft, flexible part that, when placed under load, deforms slightly to fill the gaps and irregularities between two hard parts.  These parts generally fall in two categories:

Gaskets: a general term used for a part that is pressed between two harder parts.  The part may have any shape, although flat gaskets are common.  An everyday example is the door seal in a fridge.

O-rings: these are a special type of gasket that are circular and have a round profile (like a doughnut).   O-rings are designed to fit into a groove in one of the parts and are very common in machinery.

Gasket materials must withstand the environment they are to be used in, the fluids they are to seal and the mechanical wear and tear of the application.

Silicone has a range of properties that makes it ideal for many sealing applications:

Temperature range: silicone is able to operate over a very wide range of temperatures, from -50°C to 230°C.

Chemical resistance: silicone is resistant to a wide range of chemicals: engine oil, animal and vegetable oils, brake fluid, fresh and salt water, flame resistant insulators and ozone.  Silicone is not compatible with hydrocarbon fuels, acids or alkalis.

Durability: silicone is UV resistant and exhibits extremely good weathering characteristics.

Low swelling: silicone exhibits a low level of swelling – when exposed to a variety of chemicals, the increase in volume of the silicone seal is low.

The one downside of silicone is its relatively poor resistance to abrasion and tearing.  However, silicone makes an excellent choice for seals in static applications, where the seal will not be continually rubbed or abraded.

Jehbco has produced silicone gaskets for a range of static sealing applications, including light aircraft door seals, where a large temperature range is required; marine door and window seals, where excellent weathering resistance is required; drinking water, food and medical gaskets, requiring excellent chemical resistance; gaskets for electrical enclosures; and o-rings for salt water piping, to name only a few of our applications! For any help with your application please review the Jehbco website www.Jehbco.com.au, and contact us with any questions.

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The Stress / Strain Curve

Jehbco’s pure silicone extrusions are used in a wide range of applications, from aircraft seals to sea water piping gaskets.  These applications present a wide range of operating conditions that our silicone must work under, and Jehbco works with our customers to ensure the best silicone product is chosen for your application.

In order to determine the best silicone for your application, we must be able to measure the performance of our silicone.  A range of material properties are tested to describe how our silicone will perform under different conditions.  Several of these properties are measured using a stress/strain curve.

The stress/strain curve

The stress/strain curve

The stress/strain curve is created by stretching a piece of silicone and measuring both the force required to stretch the silicone (tensile force) and how much it stretches (elongation).  The silicone is stretched until it breaks.  Since the silicone samples being stretched can be different sizes, the tensile force and elongation measurements are corrected.  Tensile force is divided by the cross sectional area of the silicone to get stress and elongation is divided by the original length of the silicone to get strain.  Stress is plotted on the y-axis and strain is plotted on the x-axis to get a stress/strain curve.   An example stress/strain curve is shown  below.

From the stress/strain curve, we can determine several important mechanical properties that tell us how the silicone behaves.  The modulus of the silicone tells us how stiff the silicone is, or how hard it is to stretch.  This is measured by calculating the slope of the first part of the stress/strain curve.  Stiff silicones will have a very steep curve, while softer silicones will have a shallower curve.

The tensile strength of the silicone is the amount of stress, or normalised force, needed to break the silicone.  This is easily read off the stress/strain curve – it is the stress at the very end of the curve, where the silicone breaks.

To ensure our product works as required, it is important that properties such as modulus and tensile strength are right for the application.  Jehbco has in-house facilities for generating stress/strain curves, to help us tailor the right product for your application.

 

For any help with your application please review the Jehbco website www.Jehbco.com.au, and contact us with any questions.

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Measuring Sealing Force

Measuring Sealing Force

Seals are used to prevent the ingress of fluid or particles in a wide range of mechanical applications.  Applications vary from traffic light enclosures to hydraulic mining equipment, fluids range from seawater to DOT brake fluid and pressures range from a couple of kilopascals to hundreds of megapascals. While some applications have been standardised, many seals require individual design.  Jehbco manufactures custom silicone extrusions for a range of non-standard sealing applications.

Seal performance is influenced by a number of factors.  These include:

  • The nature of the fluid being sealed, whether it be liquid or gas;
  • The condition of the sealing surfaces and presence of any grooves or roughness;
  • Materials;
  • Geometry;
  • Force exerted on the sealing surfaces.

This last factor, sealing force, is useful not only in estimating performance, but is essential for proper design of the sealing system.  For example, in a gasket system (Figure 1), sealing force is exerted on the gasket by a series of bolts.  To design the bolting system, the designer must know the force required to compress the gasket and form a seal.

 

Figure 1: A gasketted flanged pipe joint.

Figure 1: A gasketted flanged pipe joint.

 

Sealing force is often determined through guesswork and expensive in-field testing.  Jehbco are breaking this mould by developing custom tooling to measure force on our sealing products.  With these tools, Jehbco will be able to provide our customers with accurate estimates of sealing force required under specific conditions – for example, the force required to compress an o-ring by 20%, or the force exerted by a seal on an expansion joint when the joint is 10 mm wide.  Jehbco aims to use these tools to enhance your design processes so we can more quickly produce a silicone extrusion that meets your sealing requirements.

For more information on silicone seals and assistance, please contact us at Jehbco.

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Exploring Silicone Rubber “Blooming”

Providing a unique balance of the chemical and mechanical properties required by many of today’s more demanding industrial requirements; Silicone Rubber continues to excel in many applications from architecture to healthcare.

“Blooming” refers to the milky discoloration or white powder caused by the migration of compounds to the surface of the rubber. The presence of by-products or excess compounds can cause blooming, affecting both the functionality and aesthetics of the silicone rubber. Depending on the application, utmost purity and cleanliness of materials are essential, i.e. healthcare applications, or material aesthetics become a major material selection driving force, i.e. architecture design applications.

Exploring Silicone Rubber “Blooming”

Exploring Silicone Rubber “Blooming”

Most silicone rubber, among other silicone products, are derived from the same chemical starting material and are later differentiated. Depending on the application, tailored silicone rubber properties can be achieved through various mechanisms, such as the addition of fillers, functional fluids, and curing agents.

Curing; an essential process as to convert silicone rubber to solid from its highly-adhesive gel or liquid uncured state, is normally achieved in a catalyst-driven two-stage process; at the point of manufacture into the desired shape, and further in a prolonged post-cure process.

The choice of the catalyst system, either addition or peroxide, significantly affects the production of by-products. Addition curing system, i.e. platinum-based catalyst, the curing occurs with no byproducts, while peroxide-based curing system leaves behind byproducts, which can be an issue in food and medical applications. Both the solubility of any added fillers or agents, along with the presence of byproducts developed during curing, influence what is known as ‘Blooming’. Generally, each curing method has its own advantages and disadvantages, and based on the required end-product material properties, an optimised design selection is selected.

Accordingly, it is essential to select a reputable silicone manufacturer known for their high grades of raw materials and silicone expertise (we meet these requirements at Jehbco). By tailoring the process design per application, silicone can meet and exceed blooming and other requirements.

Overall, blooming can be influenced by the presence of added-materials to the silicone for enhanced properties and/or processability, along with the byproducts developed during the curing process.

For any help with your application, please review the Jehbco website www.jehbco.com.au, and contact us with any questions

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